Difference between revisions of "Absolute temperature scale"

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Absolute temperature scale refers to the [[Kelvin]] temperature scale.
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The term '''absolute temperature scale''' usually refers to the [[Kelvin]] temperature scale, but can also refer to the [[Rankine]] scale. These scales are based on the conventional scales for measuring temperature – [[Celsius]] in most non-US countries and [[Fahrenheit]] in the [[United States]].
  
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{{stub}}
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==Need for an absolute scale==
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[[Category:Units of temperature]]
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Chemists and physicists working with [[gas]]es came to the realization that the conventional temperature scales were not adequate for characterizing the effect of temperature on the decrease in [[volume]] and [[pressure]] of gases with the corresponding decrease in the actual temperature of the gases.
  
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To understand the absolute temperature scales one must understand the conventional scales for meanuring temperature. In the US temperature is measured using the Fahrenheit(SP?)scale. In the vast majority of the rest of the world temperature is measured using the Celsius scale. The Celsiius temperature scale was set up using the freezing point of water as the zero (0) point and the boiling point of water as the 100 point for the scale. How the Fahrenheit scale was set up is unknown to the writer.  
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Ultimately, they realized that if they could decrease the temperature of an [[Ideal Gas|ideal gas]] to a point where all [[molecular motion]] ceased, that would be a good "[[absolute zero]]" point. They found that this temperature would be -273.15 °C (-459.67 °F).
  
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However, the two scales are still in general use today throughout the world. If one wants to make a coparison between the two scales that is how to convert the temperature measurement value in one scale to the other is possible by means of a simple equation.  
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==Kelvin scale==
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The Kelvin scale, which is based on the Celsius scale, sets the absolute zero point at 0 Kelvin (or just 0K).
  
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This equation is:°F = 9/5 °C + 32. That is to say the temperture in Faharenheit is equial to 9/5 times the value in Celsius plus the constant 32.  
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Thus, the melting point of water would be 273.15 K (0&nbsp;°C + 273.15).<ref name="Britannica">[https://www.britannica.com/science/kelvin Kelvin] (www.britannica.com)</ref> Likewise, the boiling point of water at pressure 1 atm is 373.15 K (100&nbsp;°C + 273.15) and the [[triple point]] of water is at 273.16 K.
  
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If one wants to convert °C to °F the algebraic manupilation of the equation yields the following equation:
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==Rankine scale==
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Like the Kelvin scale, the absolute zero temperature on the Rankine scale is at its zero point - 0°R. However, one degree on the Rankine scale is one degree on the Fahrenheit scale.
  
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°C = 5(°F-32)/9. That is to say the temperture in Celsius is equial to 5 times the value in Faharenheit minus 32 devided by 9.  
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Thus, the freezing point of water would be 491.67 °R (32&nbsp;°F + 459.67), and the boiling point of water would be 671.67 °R (212&nbsp;°F + 459.67).  
  
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Each of these two equations can be simplified slightly as follows
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== References ==
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{{reflist}}
  
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°F = 1.8 °C + 32, and °C = (°F-32) / 1.8.
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[[Category:Units of Temperature]]
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With the foregoing in mind we can now turn to the concept of the Absolute Semperature Scales. This has been written in the plural since there are actually TWO Absolute Semperature Scales.
 
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Many years Chemists and Physicists working with gasses came to realize that the conventional temperature scales were not adequate for characterizing the effect of temperature on the decrease in volume and pressure of gases with the corresponding decrease in their actual temperature. This became evident because in trying to calsulate the decrease or increase in volume and pressure they were not able to accurately make the calculation using the conventional temperature scale.
 
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Ultimately they realized that if they could decrease the temperatue of an ideal gas to a point where all molecular motion ceased that would be ABSOLUTE ZERO. They found that such temperature would be a value of -273.16°C. For the Faharenheit scale that value would be a value of -459.6°F.
 
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Thus the melting point of water would be 0°C plus 273.16 or +273.16°K. That temperatue is called Kelvin or degrees Kelvin. Likewise the boiling point of water will be 100°C plus 273.16 or +373.16°K.
 
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The Faharenheit scale also has its complementary absolute temperature scale called the Rankin Scale. Thus the freezing point of water would be 32°F + 459.6 of +491.6°R and the boiling point of water would be 212°F + 459.6 of +671.6°R.
 
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There is other history about the development of all four of these temperatur scales and anyone who has more information that what has been presented here is free to add to this of modify it within the bounds of peer review. P.H. Metallurgical Engineer.
 
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An interesting little exercise for the reader is to determine at what temperature point the two conventional temperature scales are equal. That is to say at what temperature value are °C = °F. All the information to make that determination/calculation are contained in the foregoing information.
 

Latest revision as of 17:54, October 6, 2019

The term absolute temperature scale usually refers to the Kelvin temperature scale, but can also refer to the Rankine scale. These scales are based on the conventional scales for measuring temperature – Celsius in most non-US countries and Fahrenheit in the United States.

Need for an absolute scale

Chemists and physicists working with gases came to the realization that the conventional temperature scales were not adequate for characterizing the effect of temperature on the decrease in volume and pressure of gases with the corresponding decrease in the actual temperature of the gases.

Ultimately, they realized that if they could decrease the temperature of an ideal gas to a point where all molecular motion ceased, that would be a good "absolute zero" point. They found that this temperature would be -273.15 °C (-459.67 °F).

Kelvin scale

The Kelvin scale, which is based on the Celsius scale, sets the absolute zero point at 0 Kelvin (or just 0K).

Thus, the melting point of water would be 273.15 K (0 °C + 273.15).[1] Likewise, the boiling point of water at pressure 1 atm is 373.15 K (100 °C + 273.15) and the triple point of water is at 273.16 K.

Rankine scale

Like the Kelvin scale, the absolute zero temperature on the Rankine scale is at its zero point - 0°R. However, one degree on the Rankine scale is one degree on the Fahrenheit scale.

Thus, the freezing point of water would be 491.67 °R (32 °F + 459.67), and the boiling point of water would be 671.67 °R (212 °F + 459.67).

References

  1. ↑ Kelvin (www.britannica.com)